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Whipped Egg Whites Need Stabilizers

What's that cream of tartar for, anyway?

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One of the greatest feats of culinary magic is taking a few egg whites and whipping them into a billowy mound of cloudlike foam that fills the entire bowl. A range of recipes—from soufflés to angel food cake to lemon meringue pie—rely on whipped egg whites. But they don’t rely on whipped egg whites alone: Stabilizers are key.

There are a few different ways to stabilize whipped egg whites. Sugar and cream of tartar are two of them. When writing about egg white stabilization for a chapter in The Science of Good Cooking, Associate Editor Dan Souza and I spent a good amount of time brainstorming the best way to show, not just tell, the story of this science. But before we get too deep into the complexities of cream of tartar, let’s start simple: Egg whites. What’s even going on when you whip them up?

The Backstory

As an egg white is beaten, its proteins unfold and bond to create a meshlike network. This network coats and reinforces the surface of the air bubbles produced by the whipping. (Egg whites are composed of about 90 percent water, so these air bubbles are really floating in a sea of water.) These unfurled proteins actually increase the viscosity of the water immediately surrounding the air bubbles, enhancing their stability.

As the whites are beaten further, more air bubbles form and more proteins bond to coat and reinforce them. Eventually the whole mix puffs up and takes on the firm texture of shaving cream.

As a rule, whipped egg white foams are temporary things. The water surrounding the air bubbles will eventually succumb to the force of gravity and begin to drain away, causing the foam to separate and release its liquid. The goal? To delay this as long as possible.

Here’s where stabilizers come in. Sugar works by slowing down the drainage of moisture from the film surrounding the air bubbles in egg foams, helping the whites to remain stable, as well as to achieve maximum volume. But when it came to our experiment, Dan and I decided to concentrate on another stabilizer: cream of tartar, an acid that alters the electric charge on the proteins of the egg white, in turn reducing the interactions between protein molecules. Because this delays the formation of the foam, whipping takes longer but also results in a much more stable foam.

In the end it was pretty simple: Dan whipped up some egg whites with—and without—cream of tartar. We sat back and watched what happened.

The Experiment

Dan beat eight batches of four egg whites in a stand mixer until they achieved stiff peaks.

To half of the batches he added ¼ teaspoon of cream of tartar before whipping, while the others he left plain.

After transferring the foams to funnels set over beakers, Dan collected the water that dripped out for an hour.

The whites whipped without any stabilizers lost 23 grams of liquid on average.

The whites stabilized with cream of tartar lost less than half that amount, about 10 grams on average.

The interesting thing is that the foams made with and without cream of tartar didn’t look different—both were light and fluffy and held their stiff peaks. But they were certainly different inside, releasing a drastically different amount of liquid with time. Without stabilizers the egg foam oozed liquid, leaking at a pretty steady rate. Not so the foam with cream of tartar. While that may not make much of a difference in the texture of foams sitting in funnels, it can be a deal breaker when baking, causing weepy meringues or baked goods that deflate disastrously in the oven. And nobody wants that.

MAKE IT NOW

Our recipe for Meringue Cookies is free through October 1, 2012.

Got any egg-white–whipping questions? Leave ‘em in the comments.

About the Author: Molly Birnbaum

Molly is an associate editor of Cook’s Illustrated and the project editor of The Science of Good Cooking. She is also the author of Season to Taste: How I Lost My Sense of Smell and Found My Way, a personal inquiry into the science and psychology of the sense of smell, which was short-listed for an IACP award in Literary Food Writing. Follow her at @mollybirnbaum.

5 Comments

  • JustHughes

    Interesting. So building on that. What is the reaction that happens when using a copper bowl or sugar? Do these other methods reveal more or less stabilization? What about combining stabilizing methods? Too much or an improvement?

  • Molly Birnbaum
    Molly Birnbaum

    A great question, Justin! I spoke with Dan Souza, who did all the test kitchen experiments for The Science of Good Cooking, to get a bit more info for you. Dan says:

    Copper definitely makes a difference. The copper ions combine with conalbumin, an egg-white protein, and as a result slow the coagulation process. This means that the foam takes longer to whip and therefore more stable. The sugar dissolves in the liquid surrounding the air bubbles, increasing the viscosity of the liquid. As a result, the liquid is less apt to drain away from the air bubbles, which can cause collapse. Combining methods will make for more stable foams.

  • JustHughes

    Thanks for the update!
    So basically whipping egg whites in a copper bowl with cream of tartar and sugar means a never falling foam then eh ;) .
    Still that certainly does explain a few things about why whip the whites at the last minute before incorporating them, and why you need stabilizers.

    I would imagine this would be important especially in applications that rely on the egg whites like italian buttercream, angel food cake, meringue, and soufleé

  • pastryblonde

    I follow the recipe for the meringue on the lemon meringue pie recipe on cooksillustrated.com but when I use that meringue on custard pies (chocolate and coconut cream from illustrated and country) my pies are super wet. Is it the meringue or the custards that are letting out all the liquid?

  • Cynthia

    When making waffles I like to beat the egg whites separately and fold them into the batter for light and crispy goodness. Would stabilizers make a difference here?

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